We'll fix our symplectic manifold once and for all to be \(\mathbb{R}^2\) with its standard symplectic structure, with Darboux coordinates \(x\) and \(p\). Let \(\mathcal{A}\) be the algebra of observables on \(\mathbb{R}^2\). For technical reasons, we'll restrict to those smooth functions that are polynomially bounded in the momentum coordinate (but of course the star product makes sense in general). Let \(\mathcal{D}\) be the algebra of pseudodifferential operators on \(\mathbb{R}\). We want to define a quantization map
\[ \Psi: \mathcal{A} \to \mathcal{D} \]
such that
\[ \Psi(x) = x \in \mathcal{D} \]
\[ \Psi(p) = -i\hbar \partial \]
Out of thin air, let us define
\[ \langle q| \Psi(f) |q' \rangle = \int e^{ik(q-q')} f(\frac{q+q'}{2}, k) dk \]
This is the Weyl transform. Its inverse is the Wigner transform, given by
\[ \Phi(A, q, k) = \int e^{-ikq'} \left\langle q+\frac{q'}{2} \right| A \left| q - \frac{q'}{2} \right\rangle dq' \]
Note: I am (intentionally) ignoring all factors of \(2\pi\) involved. It's not hard to work out what they are, but annoying to keep track of them in calculations, so I won't.
Theorem For suitably well-behaved \(f\), we have \( \Phi(\Psi(f)) = f\).
Proof Using the "ignore \(2\pi\)" conventions, we have the formal identities
\[ \int e^{ikx} dx = \delta(k), \ \ \int e^{ikx} dk = \delta(x). \]
The theorem is a formal result of these:
\begin{align} \Phi(\Psi(f))(q, k) &= \int e^{-ikq'} \left\langle q + \frac{q'}{2} \right| \Psi(f) \left| q - \frac{q'}{2} \right\rangle \\\
&= \int e^{-ikq'} e^{ik'q'} f(q, k) dk' dq' \\\
&= f(q,k).
\end{align}
One may easily check that \(\Psi(x) = x\) and \(Psi(k) = -i\partial\), so this certainly gives a quantization. But why is it particularly natural? To see this, let \(Q\) be the operator of multiplication by \(x\), and let \(P\) be the operator \(-i\partial\). We'd like to take \(f(q,p)\) and replace it by \(f(Q, P)\), but we can't literally substitute like this due to order ambiguity. However, we could work formally as follows:
\begin{align}
f(Q, P) &= \int \delta(Q-q) \delta(P - p) f(q,p) dq dp \\\
&= \int e^{ik(Q-q) + iq'(P-p)} f(q,p) dq dq' dp dk.
\end{align}
In this last expression, there is no order ambiguity in the argument of the exponential (since it is a sum and not a product), and furthermore the expression itself make sense since it is the exponential of a skew-adjoint operator. So let's check that this agrees with the Weyl transform. Using a special case of the Baker-Campbell-Hausdorff formula for the Heisenberg algebra, we have
\[ e^{ik(Q-q) + iq'(P-p)} = e^{ik(Q-q)} e^{iq'(P-p)} e^{-ikq'/2} \]
Let us compute the matrix element:
\begin{align}
\langle q_1 | P | q_2 \rangle &= \int \langle q_1 | p_1 \rangle
\langle p_1 | P | p_2 \rangle \langle p_2 | q_2 \rangle dp_1 dp_2 \\\
&= \int e^{iq_1p_1 - iq_2 p_2} p_2 \delta(p_2 - p_1) dp_1 dp_2 \\\
&= \int e^{i p(q_1-q_2)} p dp.
\end{align}
Hence we find that the matrix element for the exponential is
\begin{align} \langle q_1 |e^{ik(Q-q) + iq'(P-p)} | q_2 \rangle
&= e^{-ikq'/2 + ik(q_1-q)} \langle q_1 | e^{iq'(P-p)} | q_2 \rangle \\\
&= \int e^{-ikq'/2 + ik(q_1-q) -iq'p} e^{iq'p'' + ip''(q_1-q_2)} dp'' \\\
&= \delta(q' + q_1 - q_2) e^{-ikq'/2 + ik(q_1-q) -iq'p}
\end{align}
Plugging this back into the expression for \(f(Q, P)\) we find
\begin{align}
\langle q_1 | f(Q. P) | q_2 \rangle &= \int \delta(q' + q_1 - q_2) e^{-ikq'/2 + ik(q_1-q) -iq'p}
f(q,p) dq dq' dp dk \\\
&= \int e^{ ik(q_1/2 +q_2/2-q) -ip(q_1-q_2)} f(q,p) dq dp dk \\\
&= \int e^{ip(q_1-q_2)} f(\frac{q_1+q_2}{2}, p) dp,
\end{align}
which is the original expression we gave for the Weyl transform.
Out of thin air, let us define
\[ \langle q| \Psi(f) |q' \rangle = \int e^{ik(q-q')} f(\frac{q+q'}{2}, k) dk \]
This is the Weyl transform. Its inverse is the Wigner transform, given by
\[ \Phi(A, q, k) = \int e^{-ikq'} \left\langle q+\frac{q'}{2} \right| A \left| q - \frac{q'}{2} \right\rangle dq' \]
Note: I am (intentionally) ignoring all factors of \(2\pi\) involved. It's not hard to work out what they are, but annoying to keep track of them in calculations, so I won't.
Theorem For suitably well-behaved \(f\), we have \( \Phi(\Psi(f)) = f\).
Proof Using the "ignore \(2\pi\)" conventions, we have the formal identities
\[ \int e^{ikx} dx = \delta(k), \ \ \int e^{ikx} dk = \delta(x). \]
The theorem is a formal result of these:
\begin{align} \Phi(\Psi(f))(q, k) &= \int e^{-ikq'} \left\langle q + \frac{q'}{2} \right| \Psi(f) \left| q - \frac{q'}{2} \right\rangle \\\
&= \int e^{-ikq'} e^{ik'q'} f(q, k) dk' dq' \\\
&= f(q,k).
\end{align}
One may easily check that \(\Psi(x) = x\) and \(Psi(k) = -i\partial\), so this certainly gives a quantization. But why is it particularly natural? To see this, let \(Q\) be the operator of multiplication by \(x\), and let \(P\) be the operator \(-i\partial\). We'd like to take \(f(q,p)\) and replace it by \(f(Q, P)\), but we can't literally substitute like this due to order ambiguity. However, we could work formally as follows:
\begin{align}
f(Q, P) &= \int \delta(Q-q) \delta(P - p) f(q,p) dq dp \\\
&= \int e^{ik(Q-q) + iq'(P-p)} f(q,p) dq dq' dp dk.
\end{align}
In this last expression, there is no order ambiguity in the argument of the exponential (since it is a sum and not a product), and furthermore the expression itself make sense since it is the exponential of a skew-adjoint operator. So let's check that this agrees with the Weyl transform. Using a special case of the Baker-Campbell-Hausdorff formula for the Heisenberg algebra, we have
\[ e^{ik(Q-q) + iq'(P-p)} = e^{ik(Q-q)} e^{iq'(P-p)} e^{-ikq'/2} \]
Let us compute the matrix element:
\begin{align}
\langle q_1 | P | q_2 \rangle &= \int \langle q_1 | p_1 \rangle
\langle p_1 | P | p_2 \rangle \langle p_2 | q_2 \rangle dp_1 dp_2 \\\
&= \int e^{iq_1p_1 - iq_2 p_2} p_2 \delta(p_2 - p_1) dp_1 dp_2 \\\
&= \int e^{i p(q_1-q_2)} p dp.
\end{align}
Hence we find that the matrix element for the exponential is
\begin{align} \langle q_1 |e^{ik(Q-q) + iq'(P-p)} | q_2 \rangle
&= e^{-ikq'/2 + ik(q_1-q)} \langle q_1 | e^{iq'(P-p)} | q_2 \rangle \\\
&= \int e^{-ikq'/2 + ik(q_1-q) -iq'p} e^{iq'p'' + ip''(q_1-q_2)} dp'' \\\
&= \delta(q' + q_1 - q_2) e^{-ikq'/2 + ik(q_1-q) -iq'p}
\end{align}
Plugging this back into the expression for \(f(Q, P)\) we find
\begin{align}
\langle q_1 | f(Q. P) | q_2 \rangle &= \int \delta(q' + q_1 - q_2) e^{-ikq'/2 + ik(q_1-q) -iq'p}
f(q,p) dq dq' dp dk \\\
&= \int e^{ ik(q_1/2 +q_2/2-q) -ip(q_1-q_2)} f(q,p) dq dp dk \\\
&= \int e^{ip(q_1-q_2)} f(\frac{q_1+q_2}{2}, p) dp,
\end{align}
which is the original expression we gave for the Weyl transform.
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